The false statement is the first option “Major biotic factors of ecosystems are the air (atmosphere); water (hydrosphere), and land (lithosphere)," because air, water, and land are abiotic, not biotic factors.First Option - "Major biotic factors of ecosystems are the air (atmosphere); water (hydrosphere), and land (lithosphere)."This is false because air, water, and land are abiotic factors, not biotic. Biotic factors are living things like plants, animals, bacteria.Second Option - "The Earth has a fixed amount of chemicals."True. The Earth’s total amount of chemical elements is essentially fixed.Third Option - "Chemicals cannot be lost and replaced they must be recycled."True. Chemicals cycle through ecosystems; they don’t disappear but get reused.Fourth Option - "Chemicals in a biogeochemical cycle circulate through both the living and the non-living parts of an ecosystem."True. That’s the definition of biogeochemical cycles.Fifth Option - "The oxygen cycle, the nitrogen cycle, the carbon cycle and the water cycle are important biogeochemical."True. These are classic examples of biogeochemical cycles.