We'll use the first law of thermodynamics: ΔU = Q - W, where: - ΔU = change in internal energy - Q = heat added to the system (positive) or removed from the system (negative) - W = work done by the system (positive) or on the system (negative) 1) An energy of 2145 J was added from the system, calculate the internal energy if the system performs 1165 J of work. - Q = +2145 J (heat added) - W = +1165 J (work done by the system) ΔU = Q - W = 2145 J - 1165 J = 980 J The change in internal energy is 980 J. 2) Determine the change in internal energy of the system if 97.5 J of heat energy were removed from it and if 42.25 J work was done on the system. - Q = -97.5 J (heat removed) - W = -42.25 J (work done on the system) ΔU = Q - W = -97.5 J - (-42.25 J) = -55.25 J The change in internal energy is -55.25 J. 3) A 1987.3 J of energy was removed from a gas. The gas was compressed at a pressure of 890 Pa from an initial volume of 6 m³ to a final volume of 3.5 m³. Calculate the WORK done and the change in Internal Energy. - Q = -1987.3 J (heat removed) - W = PΔV = 890 Pa * (3.5 m³ - 6 m³) = 890 Pa * (-2.5 m³) = -2225 J (work done on the gas during compression) ΔU = Q - W = -1987.3 J - (-2225 J) = 237.7 J Work done = -2225 JChange in Internal Energy = 237.7 J 4) 3520.9 J of heat was added to the system. The gas expands from 0.5 m³ to 1.23 m³ at a pressure of 43000 Pa. Calculate the WORK done and CHANGE IN INTERNAL ENERGY. - Q = +3520.9 J (heat added) - W = PΔV = 43000 Pa * (1.23 m³ - 0.5 m³) = 43000 Pa * 0.73 m³ = 31390 J (work done by the gas during expansion) ΔU = Q - W = 3520.9 J - 31390 J = -27869.1 J Work done = 31390 JChange in Internal Energy = -27869.1 J Remember that work is positive when done by the system (expansion) and negative when done on the system (compression). Heat is positive when added and negative when removed.